CO<inline-formula><tex-math id="M1">\begin{document}$ _{2} $\end{document}</tex-math></inline-formula> Reduction on Metal-Doped SnO<inline-formula><tex-math id="M2">\begin{document}$ _{2} $\end{document}</tex-math></inline-formula>(110) Surface Catalysts: Manipulating the Product by Changing the Ratio of Sn:O

Lei Cui; DaDi Zhang; Yuan Kong; Xiao Zheng

doi:10.1063/1674-0068/cjcp2104077

Volume 35 Issue 3

Jun. 2022

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Article Navigation > Chinese Journal of Chemical Physics > 2022 > 35(3): 413-421

Lei Cui, DaDi Zhang, Yuan Kong, Xiao Zheng. CO$ _{2} $ Reduction on Metal-Doped SnO$ _{2} $(110) Surface Catalysts: Manipulating the Product by Changing the Ratio of Sn:O[J]. Chinese Journal of Chemical Physics , 2022, 35(3): 413-421. doi: 10.1063/1674-0068/cjcp2104077

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Lei Cui, DaDi Zhang, Yuan Kong, Xiao Zheng. CO$ _{2} $ Reduction on Metal-Doped SnO$ _{2} $(110) Surface Catalysts: Manipulating the Product by Changing the Ratio of Sn:O[J]. Chinese Journal of Chemical Physics , 2022, 35(3): 413-421. doi: 10.1063/1674-0068/cjcp2104077

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CO$ _{2} $ Reduction on Metal-Doped SnO$ _{2} $(110) Surface Catalysts: Manipulating the Product by Changing the Ratio of Sn:O

doi: 10.1063/1674-0068/cjcp2104077

Lei Cui^{a, b},
DaDi Zhang^{b
,
,},
Yuan Kong^{a
,
,},
Xiao Zheng^a

a.
Department of Chemical Physics and Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China
b.
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China

More Information

Corresponding author: Zhang DaDi, E-mail: zhangdadi@ustc.edu.cn; Kong Yuan, E-mail: kongyuan@ustc.edu.cn
Received Date: 2021-04-27
Accepted Date: 2021-05-20
Publish Date: 2022-06-27

Abstract

Abstract

The electrocatalytic carbon dioxide reduction reaction (CO₂RR) producing HCOOH and CO is one of the most promising approaches for storing renewable electricity as chemical energy in fuels. SnO₂ is a good catalyst for CO₂-to-HCOOH or CO₂-to-CO conversion, with different crystal planes participating the catalytic process. Among them, (110) surface SnO₂ is very stable and easy to synthesisze. By changing the ratio of Sn: O for SnO₂(110), we have two typical SnO₂ thin films: fully oxidized (stoichiometric) and partially reduced. In this work, we are concerned with different metals (Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Os, Ir, Pt, and Au)-doped SnO₂(110) with different activity and selectivity for CO₂RR. All these changes are manipulated by adjusting the ratio of Sn: O in (110) surface. The results show that stochiometric and reduced Cu/Ag doped SnO₂(110) have different selectivity for CO₂RR. More specifically, stochiometric Cu/Ag-doped SnO₂(110) tends to generate CO(g). Meanwhile, the reduced surface tends to generate HCOOH(g). Moreover, we also considered the competitive hydrogen evolution reaction (HER). The catalysts SnO₂(110) doped by Ru, Rh, Pd, Os, Ir, and Pt have high activity for HER, and others are good catalysts for CO₂RR.
- Carbon dioxide reduction reaction,
- DFT calculation,
- Product manipulation,

^†Part of Special Topic "Quantum and Classical Dynamics in Chemistry" in the 32nd Chinese Chemical Society Congress.

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References(63)

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