Bio-syngas Converting to Liquid Fuels over Co Modified Fe<inline-formula><tex-math id="M1">\begin{document}$_{3}$\end{document}</tex-math></inline-formula>O<inline-formula><tex-math id="M2">\begin{document}$_{4}$\end{document}</tex-math></inline-formula>-MnO<inline-formula><tex-math id="M3">\begin{document}$_{2}$\end{document}</tex-math></inline-formula> Catalysts

Jie Wang; Ying Xiang; Yi-yuan Ding; Yan-fei Xu; Xiang-hui Kong; Guang-yuan Ma; Chanatip Samart; Ming-yue Ding

doi:10.1063/1674-0068/cjcp1904086

Volume 32 Issue 6

Dec. 2019

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Article Navigation > Chinese Journal of Chemical Physics > 2019 > 32(6): 721-726

Jie Wang, Ying Xiang, Yi-yuan Ding, Yan-fei Xu, Xiang-hui Kong, Guang-yuan Ma, Chanatip Samart, Ming-yue Ding. Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 721-726. doi: 10.1063/1674-0068/cjcp1904086

Citation:

Jie Wang, Ying Xiang, Yi-yuan Ding, Yan-fei Xu, Xiang-hui Kong, Guang-yuan Ma, Chanatip Samart, Ming-yue Ding. Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 721-726. doi: 10.1063/1674-0068/cjcp1904086

Citation:

Jie Wang, Ying Xiang, Yi-yuan Ding, Yan-fei Xu, Xiang-hui Kong, Guang-yuan Ma, Chanatip Samart, Ming-yue Ding. Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts[J]. Chinese Journal of Chemical Physics , 2019, 32(6): 721-726. doi: 10.1063/1674-0068/cjcp1904086

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Bio-syngas Converting to Liquid Fuels over Co Modified Fe$_{3}$O$_{4}$-MnO$_{2}$ Catalysts

doi: 10.1063/1674-0068/cjcp1904086

a.
School of Power and Mechanical Engineering, Hubei International Scientific and Technological Cooperation Base of Sustainable Resource and Energy, Hubei Province Key Laboratory of Accountrement Technique in Fluid Machinery & Power Engineering, Wuhan University, Wuhan 430072, China
b.
Department of Chemistry, Faculty of Science and Technology, Thammasat University, Rangsit Campus, Klongluang, Pathumtani 12120, Thailand
c.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

More Information

Corresponding author: Ming-yue Ding, E-mail: dingmy@whu.edu.cn
Received Date: 2019-04-29
Accepted Date: 2019-06-24
Publish Date: 2019-12-27

Abstract

Abstract

A bifunctional Co modified Fe$_3$O$_4$-Mn catalyst was prepared for Fischer-Tropsch synthesis (FTS). The influence of Co loading on the synergistic effect of Fe-Co as well as FTS performance over Fe$_1$Co$_x$Mn$_1$ catalysts was studied. Incorporation of Co species into the Fe$_3$O$_4$-Mn catalyst promoted the reduction of iron oxides, increasing iron active sites during FTS. Moreover, the adding of Co species enhanced the electron transfer from Fe to Co metal, which strengthened the synergistic effect of Fe-Co, improving the catalytic performance. The Fe$_1$Co$_x$Mn$_1$ catalyst with higher Co loading promoted further the hydrogenation ability, favoring the shifting of the product distribution towards shorter hydrocarbons. Under optimized conditions of 280 ℃, 2.0 MPa and 3000 h$^{-1}$, the highest yield of liquid fuels was obtained for the Fe$_1$Co$_1$Mn$_1$ catalyst.

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References(35)

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