Hong-guang Song, Yan-jun Ding, Jia Yang, Hang-xun Xu. A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction[J]. Chinese Journal of Chemical Physics , 2016, 29(6): 693-698. doi: 10.1063/1674-0068/29/cjcp1605115
Citation: Hong-guang Song, Yan-jun Ding, Jia Yang, Hang-xun Xu. A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction[J]. Chinese Journal of Chemical Physics , 2016, 29(6): 693-698. doi: 10.1063/1674-0068/29/cjcp1605115

A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction

doi: 10.1063/1674-0068/29/cjcp1605115
  • Received Date: 2016-05-26
  • Rev Recd Date: 2016-05-31
  • Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped mesoporous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The electrocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.
  • 加载中
  • [1] B. C. H. Steele and A. Heinzel, Nature 414, 345(2001).
    [2] S. Chu and A. Majumdar, Nature 448, 294(2012).
    [3] M. K. Debe, Nature 486, 43(2012).
    [4] H. A. Gasteiger, S. S. Kocha, B. Sompalli, and F. T. Wagner, Appl. Catal. B 56, 9(2005).
    [5] X. Ge, A. Sumboja, D. Wuu, T. An, B. Li, F. W. Thomas Goh, T. S. Andy Hor, Y. Zong, and Z. Liu, ACS Catal. 5, 4643(2015).
    [6] I. Katsounaros, S. Cherevko, A. R. Zeradjanin, and K. J. J. Mayrhofer, Angew. Chem. Int. Ed. 53, 102(2014).
    [7] Y. Nie, L. Li, and Z. Wei, Chem. Soc. Rev. 44, 2168(2015).
    [8] Y. Bing, H. Liu, L. Zhang, D. Ghosha, and J. Zhang, Chem. Soc. Rev. 39, 2184(2010).
    [9] R. Bashyam and P. Zelenay, Nature 443, 63(2006).
    [10] R. Borup, J. Meyers, B. Pivovar, Y. S. Kim, R. Mukundan, N. Garland, D. Myers, M. Wilson, F. Garzon, D. Wood, P. Zelenay, K. More, K. Stroh, T. Zawodzinski, J. Boncella, J. E. McGrath, M. Inaba, K. Miyatake, M. Hori, K. Ota, Z. Ogumi, S. Miyata, A. Nishikata, Z. Siroma, Y. Uchimoto, K. Yasuda, K. Kimijima, and N. Iwashita, Chem. Rev. 107, 3904(2007).
    [11] Y. G. Li, W. Zhou, H. L. Wang, L. M. Xie, Y. Y. Liang, F. Wei, J. C. Idrobo, S. J. Pennycook, and H. J. Dai, Nat. Nanotechnol. 7, 394(2012).
    [12] Z. Yang, Y. Xia, and R. Mokaya, J. Am. Chem. Soc. 129, 1673(2007).
    [13] J. Lee, J. Kim, and T. Hyeon, Adv. Mater. 18, 2073(2006).
    [14] C. Liang, Z. Li, and S. Dai, Angew. Chem. Int. Ed. 47, 3696(2008).
    [15] L. Dai, Y. Xue, L. Qu, H. J. Choi, and J. B. Baek, Chem. Rev. 115, 4823(2015).
    [16] J. Duan, S. Chen, M. Jaroniec, and S. Z. Qiao, ACS Catal. 5, 5207(2015)
    [17] D. W. Wang and D. Su, Energy Environ. Sci. 7, 576(2014).
    [18] H. Shi, Y. Shen, F. He, Y. Li, A. Liu, S. Liu, and Y. Zhang, J. Mater. Chem. A 2, 15704(2014).
    [19] Y. Hu, J. O. Jensen, W. Zhang, L. N. Cleemann, W. Xing, N. J. Bjerrum, and Q. Li, Angew. Chem. Int. Ed. 53, 3675(2014).
    [20] J. R. Long and O. M. Yaghi, Chem. Soc. Rev. 38, 1213(2009).
    [21] J. S. Li, S. L. Li, Y. J. Tang, K. Li, L. Zhou, N. Kong, Y. Q. Lan, J. C. Bao, and Z. H. Dai, Sci. Rep. 4, 5130(2014).
    [22] S. Ma, G. A. Goenaga, A. V. Call, and D. J. Liu, Chem. Eur. J. 17, 2063(2011).
    [23] P. Su, H. Xiao, J. Zhao, Y. Yao, Z. Shao, C. Li, and Q. Yang, Chem. Sci. 4, 2941(2013).
    [24] E. Y. Choi, C. A. Wray, C. Hu, and W. Choe, CrystEngComm 11, 553(2009).
    [25] G. Wu, K. L. More, C. M. Johnston, and P. Zelenay, Science 332, 443(2011).
    [26] Y. Z. Chen, C. Wang, Z. Y. Wu, Y. Xiong, Q. Xu, S. H. Yu, and H. L. Jiang, Adv. Mater. 27, 5010(2015).
    [27] Z. Yan, M. Cai, and P. K. Shen, J. Mater. Chem. 22, 2133(2012).
    [28] J. Tang, R. R. Salunkhe, J. Liu, N. L. Torad, M. Imura, S. Furukawa, and Y. Yamauchi, J. Am. Chem. Soc. 137, 1572(2015).
    [29] Z. S. Wu, L. Chen, J. Liu, K. Parvez, H. Liang, J. Shu, H. Sachdev, R. Graf, X. Feng, and K. Mllen, Adv. Mater. 26, 1450(2014).
    [30] S. Zhao, H. Yin, L. Du, L. He, K. Zhao, L. Chang, G. Yin, H. Zhao, S. Liu, and Z. Tang, ACS Nano 8, 12660(2014).
    [31] Q. Lin, X. Bu, A. Kong, C. Mao, X. Zhao, F. Bu, and P. Feng, J. Am. Chem. Soc. 137, 2235(2015).
  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Article Metrics

Article views(1019) PDF downloads(589) Cited by()

Proportional views
Related

A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction

doi: 10.1063/1674-0068/29/cjcp1605115

Abstract: Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped mesoporous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The electrocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.

Hong-guang Song, Yan-jun Ding, Jia Yang, Hang-xun Xu. A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction[J]. Chinese Journal of Chemical Physics , 2016, 29(6): 693-698. doi: 10.1063/1674-0068/29/cjcp1605115
Citation: Hong-guang Song, Yan-jun Ding, Jia Yang, Hang-xun Xu. A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction[J]. Chinese Journal of Chemical Physics , 2016, 29(6): 693-698. doi: 10.1063/1674-0068/29/cjcp1605115
Reference (31)

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return