A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction

Hong-guang Song; Yan-jun Ding; Jia Yang; Hang-xun Xu

doi:10.1063/1674-0068/29/cjcp1605115

Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped mesoporous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The electrocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.

CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Received Date: 2016-05-26

Rev Recd Date: 2016-05-31

Key words:

Abstract: Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped mesoporous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The electrocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.

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A Layer-Structured Metal-Organic Framework-Derived Mesoporous Carbon for Efficient Oxygen Reduction Reaction

doi: 10.1063/1674-0068/29/cjcp1605115

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