Cheng-bing Qin, Jian-zheng Zang, De-ping Zhang, Qun Zhang, Yang Chen. Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State[J]. Chinese Journal of Chemical Physics , 2013, 26(2): 140-144. doi: 10.1063/1674-0068/26/02/140-144
Citation: Cheng-bing Qin, Jian-zheng Zang, De-ping Zhang, Qun Zhang, Yang Chen. Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State[J]. Chinese Journal of Chemical Physics , 2013, 26(2): 140-144. doi: 10.1063/1674-0068/26/02/140-144

Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State

doi: 10.1063/1674-0068/26/02/140-144
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.21273212 and No.21173205), the National Key Basic Research Pro-gram of China (No.2010CB923302), the Chinese Academy of Sciences (No.KJCX2-YW-N24), the Fun-damental Research Funds for the Central Universities of China (No.WK2340000012), and the University of Science and Technology of China-National Synchrotron Radiation Laboratory (No.KY2340000021).
  • Received Date: 2013-01-31
  • Laser-induced fluorescence excitation spectra of jet-cooled NiS molecules were recorded in the energy range of 12200-13550 cm-1. Four vibronic bands with rotational structure have been observed and assigned to the [12.4]30- -X30- transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.
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Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State

doi: 10.1063/1674-0068/26/02/140-144
Funds:  This work was supported by the National Natu-ral Science Foundation of China (No.21273212 and No.21173205), the National Key Basic Research Pro-gram of China (No.2010CB923302), the Chinese Academy of Sciences (No.KJCX2-YW-N24), the Fun-damental Research Funds for the Central Universities of China (No.WK2340000012), and the University of Science and Technology of China-National Synchrotron Radiation Laboratory (No.KY2340000021).

Abstract: Laser-induced fluorescence excitation spectra of jet-cooled NiS molecules were recorded in the energy range of 12200-13550 cm-1. Four vibronic bands with rotational structure have been observed and assigned to the [12.4]30- -X30- transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.

Cheng-bing Qin, Jian-zheng Zang, De-ping Zhang, Qun Zhang, Yang Chen. Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State[J]. Chinese Journal of Chemical Physics , 2013, 26(2): 140-144. doi: 10.1063/1674-0068/26/02/140-144
Citation: Cheng-bing Qin, Jian-zheng Zang, De-ping Zhang, Qun Zhang, Yang Chen. Laser-induced Fluorescence Spectroscopy of NiS: Identification of a Low-lying Electronic State[J]. Chinese Journal of Chemical Physics , 2013, 26(2): 140-144. doi: 10.1063/1674-0068/26/02/140-144

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