Abstract: The progress in the quantum coherent controlling of chemical reactions is briefly reviewed. The controlling was firstly realized by modulating the phasa angle between one-photon and three-photon excitation of some molecules. The fluorescence intensities of atom in gaseous phase or molecules in liquid phase，as well as the dissociation branching of molecules were also controlled by self-optimizing the phase and the amplitude of an ultrafast laser pules. Some new possible propress of coherent control may appearin strong laser field，in condense phase or on catalysts.