A Temperature-Programmed Desorption Spectrometer Combining Minimum Gas Load, Fast Substrate Replacement, and Comprehensive Temperature Control

Shucai Xia Shanshan Dong Huizhi Xie Jialong Li Tianjun Wang Weiqing Zhang Li Che Zefeng Ren Dongxu Dai Xueming Yang Chuanyao Zhou

Shucai Xia, Shanshan Dong, Huizhi Xie, Jialong Li, Tianjun Wang, Weiqing Zhang, Li Che, Zefeng Ren, Dongxu Dai, Xueming Yang, Chuanyao Zhou. A Temperature-Programmed Desorption Spectrometer Combining Minimum Gas Load, Fast Substrate Replacement, and Comprehensive Temperature Control[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2212180
Citation: Shucai Xia, Shanshan Dong, Huizhi Xie, Jialong Li, Tianjun Wang, Weiqing Zhang, Li Che, Zefeng Ren, Dongxu Dai, Xueming Yang, Chuanyao Zhou. A Temperature-Programmed Desorption Spectrometer Combining Minimum Gas Load, Fast Substrate Replacement, and Comprehensive Temperature Control[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2212180

doi: 10.1063/1674-0068/cjcp2212180

A Temperature-Programmed Desorption Spectrometer Combining Minimum Gas Load, Fast Substrate Replacement, and Comprehensive Temperature Control

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  • Figure  4.  (a) Schematic of the sample stage located at the bottom of manipulator with a sample plate inserted. (b) Temperature curve for two consecutive heating-cooling cycles.

    Figure  1.  Three-dimensional design of the UHV system. Devices and sub-systems are shown in different colors.

    Figure  2.  Schematic of the gas handling system (GHS).

    Figure  3.  Detailed structure of the MCA molecular beam doser, which is mounted in a linear translator. The inset is an enlarged view of the head of doser.

    Figure  5.  (a) Water TPD spectra from HOPG. Inset of (a) shows the integrated area of spectra as a function of water dosage and a linear fit. (b) and (c) are the Arrhenius plot based on the leading edge of TPD spectra with water dosage of 2 L and 8 L. Linear fittings of the two plots yield desorption energies of 44.45 ± 1.21 kJ/mol and 44.23 ± 0.47 kJ/mol, respectively.

    Figure  6.  TPD spectrum of 2.8 ML water on rutile TiO2(110) collected with a heating rate of 2 K/s. The upper inset shows the enlarged zone around 460 K, and the lower inset is the ball and stick model of rutile TiO2(110) substrate with water molecules adsorbed at different sites.

    Figure  7.  TPD spectra of methanol (m/z=31) from TiO2(110) as a function of methoxy anion coverage. The spectra are collected with a heating rate of 2 K/s.

    Figure  8.  (a) TPD spectra (m/z = 29) of 0.3 ML methoxy anions covered TiO2(110) surface before and after 405 nm light illumination, respectively. (b) By subtracting the contribution from methanol of the TPD spectrum, the m/z = 29 signal of formaldehyde is obtained.

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出版历程
  • 收稿日期:  2022-12-26
  • 录用日期:  2023-02-22
  • 网络出版日期:  2023-02-24

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