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OCS分子在128 nm附近的光解动力学研究:S(^3P_J=2, 1, 0)、S(^1D_2)以及S(^1S_0)产物通道

Photodissociation Dynamics of OCS Near 128 nm: S(^3P_J=2, 1, 0), S(^1D_2) and S(^1S_0) Channels

  • 摘要: 本文利用时间切片离子成像技术对OCS分子进行了真空紫外波段的光解动力学研究.在四个光解光波长(从129.32到126.08 nm)下测量了硫原子解离产物S(^3P_J=2, 1, 0)、S(^1D_2)、S(^1S_0)的速度影像,并从中清晰地发现了四个主要的解离产物通道:S(^3P_J=2, 1, 0)+CO(X^1\Sigma^+),S(^3P_J=2, 1, 0)+CO(A^3\Pi),S(^1D_2)\+CO(X^1\Sigma^+)和S(^1S_0)+CO(X^1\Sigma^+).在实验影像中,产物CO分子的部分振动态结构能够得到分辨.实验还获取解离产物总平动能谱,产物分支比和角分布.对实验结果进行分析显示除绝热解离通道S(^3P_J=2, 1, 0)+CO(A^3\Pi)之外,在其他三个产物通道中非绝热效应都起到非常重要的作用.

     

    Abstract: Here we report the study of the photodissociation dynamics of carbonyl sulfide in the vacuum ultraviolet region using the time-sliced velocity map ion imaging technique. Images of S(^3P_J=2, 1, 0), S(^1D_2) and S(^1S_0) products were measured at four photolysis wavelengths of 129.32, 128.14, 126.99, and 126.08 nm, respectively. Four main dissociation channels: S(^3P_J=2, 1, 0)+CO(X^1\Sigma^+), S(^3P_J=2, 1, 0)+CO(A^3\Pi), S(^1D_2)+CO(X^1\Sigma^+) and S(^1S_0)+CO(X^1\Sigma^+) channels, have been clearly observed and identified. Vibrational states of the CO co-products were partially resolved in the experimental images. From these images, the product total kinetic energy releases, the branching ratios and angular distributions of products have been derived. While the S(^3P_J=2, 1, 0)+CO(A^3\Pi) product channel is formed through the adiabatic dissociation process after the excitation to the (3^1\Sigma^+) excited state, the results suggest that strong nonadiabatic coupling plays an important role in the formation of other three channels.

     

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