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1-庚烯/空气的高压层流火焰传播研究

Investigation on 1-Heptene/Air Laminar Flame Propagation under Elevated Pressures

  • 摘要: 本文使用定容圆柱形燃烧弹,在初始温度373 K和初始压力1、2、5、10 atm的条件下,对当量比从0.7到1.5的1-庚烯/空气混合物的层流火焰传播进行了研究. 利用记录的纹影图像处理得到层流火焰传播速度和马克斯坦长度. 基于先前报道的1-己烯燃烧反应动力学模型,发展了1-庚烯的模型. 该模型验证了本工作测量的1-庚烯层流火焰传播速度数据及文献中的1-庚烯着火延迟时间数据. 通过开展敏感性分析和路径分析,帮助理解了1-庚烯在不同压力下的高温化学及其对层流火焰传播的影响. 另外,比较了1-庚烯/空气和先前报道的正庚烷/空气的层流火焰传播. 由于更强的放热性及反应活性,1-庚烯/空气的层流火焰传播速度在绝大多数条件下均快于正庚烷/空气的结果.

     

    Abstract: The laminar flame propagation of 1-heptene/air mixtures covering equivalence ratios from 0.7 to 1.5 is investigated in a constant-volume cylindrical combustion vessel at 373 K and elevated pressures (1, 2, 5, and 10 atm). Laminar flame speed and Markstein length are derived from the recorded schlieren images. A kinetic model of 1-heptene combustion is developed based on our previous kinetic model of 1-hexene. The model is validated against the laminar flame speed data measured in this work and the ignition delay time data in literature. Modeling analyses, such as sensitivity analysis and rate of production analysis, are performed to help understand the high temperature chemistry of 1-heptene under various pressures and its influence on the laminar flame propagation. Furthermore, the laminar flame propagation of 1-heptene/air mixtures is compared with that of n-heptane/air mixtures reported in our previous work. The laminar flame speed values of 1-heptene/air mixtures are observed to be faster than those of n-heptane/air mixtures under most conditions due to the enhanced exothermicity and reactivity.

     

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