Studies on the Paramagnetic Relaxation in the Solution with a few of Paramagnetic Ions and a lot of Ligands(Ⅱ)
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Abstract
A new explanation of the broadening of NMR peaks of the solution with a few of paramagnetic ions and a lot of ligands is reported in the paper. The new points about the explanation have been proved true in the experiment. In the course of the prove, the value of 1/Gi or 1/T2l have been calculated. Because 1/Gi or 1/T21 gets rid of the effect of the exchange between ligands, the distance between paramagnetic ions and carbonic atoms of ligands can be caculaed with 1/Gi or 1/T21 by means of S-B equation. So contiguration of the complexes can be gained.
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