Pan Huiyun, Zhang Botao. Kinetic Phase Transition for the Oxidation of SO2 on a Catalytic Surface[J]. Chinese Journal of Chemical Physics , 1995, 8(4): 296-301.
Citation:
Pan Huiyun, Zhang Botao. Kinetic Phase Transition for the Oxidation of SO2 on a Catalytic Surface[J]. Chinese Journal of Chemical Physics , 1995, 8(4): 296-301.
Pan Huiyun, Zhang Botao. Kinetic Phase Transition for the Oxidation of SO2 on a Catalytic Surface[J]. Chinese Journal of Chemical Physics , 1995, 8(4): 296-301.
Citation:
Pan Huiyun, Zhang Botao. Kinetic Phase Transition for the Oxidation of SO2 on a Catalytic Surface[J]. Chinese Journal of Chemical Physics , 1995, 8(4): 296-301.
Kinetic Phase Transition for the Oxidation of SO2 on a Catalytic Surface
We introduce a "partial simulation" method to calculate the kinetic phase transitions for the oxidation of SO2 on a catalytic surface.For the pure Langmuir-Hinshelwood mechanism, The reaction system exhibits three phases:the SO2 -poisoned,the O-poisoned and the reactive phase, in consistence with the Monte-Carlo results. When the Eley-Rideal mechanism also takes part in the process,the O-poisoned phase disappears.
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