Investigations of the g Factors and ZFS in Cdcl2: V2+ and CdI2: V2+
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Abstract
EPR parameters g factors and zero field splittings(ZFS) for V2+ ions in the CdCl2:V2+ and CdI2:V2+ crystals have been stuted.In the calculation,contributions of spin orbit (SO) couplings from not only the central transition metal ions but also the ligands are considered.The results suggest that the calculation of EPR prameters for sone conplexes possessing strong cobalence and large SO coupling constant of ligands should use the two SO coupling parameter model.
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