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Minfu Zhao, Shanshan Niu, Qiguo Tian, Jing Yang, Xu Shan, Xiangjun Chen. Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide[J]. Chinese Journal of Chemical Physics .
Citation: Minfu Zhao, Shanshan Niu, Qiguo Tian, Jing Yang, Xu Shan, Xiangjun Chen. Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide[J]. Chinese Journal of Chemical Physics .

Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide

  • Received Date: 2020-10-26
  • Accepted Date: 2020-11-05
  • Rev Recd Date: 2020-11-03
  • Available Online: 2020-11-11
  • The binding energy spectrum (BES) and electron momentum profiles (EMPs) of the inner orbitals of methyl iodide have been measured using an electron momentum spectrometer at the impact energy of 1200 eV plus binding energy. Two peaks in the BES, arising from the spin-orbit (SO) splitting, are observed and the corresponding EMPs are obtained. Relativistic density functional calculations are performed to elucidate the experimental EMPs of two SO splitting components, showing agreement with each other except for the intensity in low momentum region. The measured high intensity in the low momentum region can be further explained by the distorted wave calculation.
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通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide

Abstract: The binding energy spectrum (BES) and electron momentum profiles (EMPs) of the inner orbitals of methyl iodide have been measured using an electron momentum spectrometer at the impact energy of 1200 eV plus binding energy. Two peaks in the BES, arising from the spin-orbit (SO) splitting, are observed and the corresponding EMPs are obtained. Relativistic density functional calculations are performed to elucidate the experimental EMPs of two SO splitting components, showing agreement with each other except for the intensity in low momentum region. The measured high intensity in the low momentum region can be further explained by the distorted wave calculation.

Minfu Zhao, Shanshan Niu, Qiguo Tian, Jing Yang, Xu Shan, Xiangjun Chen. Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide[J]. Chinese Journal of Chemical Physics .
Citation: Minfu Zhao, Shanshan Niu, Qiguo Tian, Jing Yang, Xu Shan, Xiangjun Chen. Electron Momentum Spectroscopy Study on the Inner Orbitals of Methyl iodide[J]. Chinese Journal of Chemical Physics .

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