Relabeling of the Rydberg and Doubly Excited States of Li2

68 electronic states of 7Li2 observed and/or calculated have been relabeled according to the dominant hydrogenic nlλ characters of the Rydberg orbitals and classified as core-penetrating vs core-nonpenetrating states. The perturbations between doubly excited valence states and Rydberg states are discussed. The significance of this labeling is also discussed.