Selective Preparation of Light Olefins from Cellulose-Derived Fermentation Intermediates

Danfeng Lou; Rui Zhang; Yuehui Luo; Quanxin Li

doi:10.1063/1674-0068/cjcp2301007

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Danfeng Lou, Rui Zhang, Yuehui Luo, Quanxin Li. Selective Preparation of Light Olefins from Cellulose-Derived Fermentation Intermediates[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2301007

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Danfeng Lou, Rui Zhang, Yuehui Luo, Quanxin Li. Selective Preparation of Light Olefins from Cellulose-Derived Fermentation Intermediates[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2301007

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Selective Preparation of Light Olefins from Cellulose-Derived Fermentation Intermediates

doi: 10.1063/1674-0068/cjcp2301007

Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China

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Corresponding author: E-mail: liqx@ustc.edu.cn
Received Date: 2023-01-17
Accepted Date: 2023-03-20

Available Online: 2023-03-22

Abstract

Abstract

Directional synthesis of bio-based light olefins has great significance for promoting sustainable development of chemical industry. Present work proves that light olefins can be selectively prepared from the cellulose-derived acetone-butanol-ethanol. This transformation has been achieved by coupling cellulose fermentation and acetone-butanol-ethanol catalytic dehydration over the Ce@SAPO-34 catalyst. The active sites and reusability of the catalyst were investigated. High acetone-butanol-ethanol conversion (91.9%) and high olefin selectivity (86.1%) are achieved. Based on the study of the individual components in acetone-butanol-ethanol, the reaction pathways are put forward.
- Cellulose,
- Acetone-butanol-ethanol fermentation intermediate,
- Light olefin,
- Ce@SAPO-34 catalyst

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References(40)

References

[1]	J. P. Ma, S. Shi, X. Q. Jia, F. Xia, H. Ma, J. Gao, and J. Xie, J. Energy Chem. 36, 74 (2019). doi: 10.1016/j.jechem.2019.04.026
[2]	L. F. Zhu, X. Fu, Y. X. Hu, and C. W. Hu, ChemSusChem 13, 4812 (2020). doi: 10.1002/cssc.202001341
[3]	X. Liu, T. F. Li, S. B. Wu, H. Ma, and Y. H. Yin, Bioresour. Technol. 310, 123460 (2020). doi: 10.1016/j.biortech.2020.123460
[4]	Z. Y. Li, Z. P. Zhong, B. Zhang, W. Wang, G. V. S. Seuﬁtelli, and F. L. P. Resende, Waste Manage. 102, 561 (2020). doi: 10.1016/j.wasman.2019.11.012
[5]	S. K. Bhatia, S. H. Kim, J. J. Yoon, and Y. H. Yang, Energy Convers. Manage. 148, 1142 (2017). doi: 10.1016/j.enconman.2017.06.073
[6]	Y. Guo, Y. Liu, M. D. Guan, H. C. Tang, Z. L. Wang, L. H. Lin, and H. Pang, RSC Adv. 12, 18848 (2022). doi: 10.1039/D1RA09396G
[7]	P. X. Wang, J. Zhang, J. Feng, S. J. Wang, L. Guo, Y. F. Wang, Y. Y. Lee, S. Taylor, T. McDonald, and Y. Wang, Bioresour. Technol. 281, 217 (2019). doi: 10.1016/j.biortech.2019.02.096
[8]	C. Xue, M. Liu, X. W. Guo, E. P. Hudson, L. J. Chen, F. W. Bai, F. F. Liu, and S. T. Yang, Green Chem. 19, 660 (2017). doi: 10.1039/C6GC02546C
[9]	Z. Q. Wen, R. Ledesma-Amaro, M. R. Lu, M. J. Jin, and S. Yang, ACS Synth. Biol. 9, 304 (2020). doi: 10.1021/acssynbio.9b00331
[10]	F. Cebreiros, M. D. Ferrari, and C. Lareo, Ind. Crop. Prod. 134, 50 (2019). doi: 10.1016/j.indcrop.2019.03.059
[11]	J. W. Wu, L. L. Dong, B. F. Liu, D. F. Xing, C. S. Zhou, Q. Wang, X. K. Wu, L. P. Feng, and G. L. Cao, Environ. Res. 186, 109580 (2020). doi: 10.1016/j.envres.2020.109580
[12]	P. Anbarasan, Z. C. Baer, S. Sreekumar, E. Gross, J. B. Binder, H. W. Blanch, D. S. Clark, and F. D. Toste, Nature 491, 235 (2012). doi: 10.1038/nature11594
[13]	M. A. Diaz-Perez and J. C. Serrano-Ruiz, Molecules 25, 802 (2020). doi: 10.3390/molecules25040802
[14]	B. H. H. Goh, C. T. Chong, H. C. Ong, T. Seljak, T. Katrasnik, V. Jozsa, J. H. Ng, B. Tian, S. Karmarkar, and V. Ashokkumarh, Energy Convers. Manage. 251, 114974 (2022). doi: 10.1016/j.enconman.2021.114974
[15]	Y. Chen, Y. L. Wu, L. Tao, B. Dai, M. D. Yang, Z. Chen, and X. Y. Zhu, J. Ind. Eng. Chem. 16, 717 (2010). doi: 10.1016/j.jiec.2010.07.013
[16]	M. A. Perez, R. Bringue, M. Iborra, J. Tejero, and F. Cunill, Appl. Catal. A Gen. 482, 38 (2014). doi: 10.1016/j.apcata.2014.05.017
[17]	K. Cheng, B. Gu, X. Liu, J. Kang, Q. Zhang, and Y. Wang, Angew. Chem. Int. Ed. 55, 4725 (2016). doi: 10.1002/anie.201601208
[18]	S. X. Bai, F. F. Liu, B. L. Huang, F. Li, H. P. Lin, T. Wu, M. Z. Sun, J. B. Wu, Q. Shao, Y. Xu, and X. Q. Huang, Nat. Commun. 11, 954 (2020). doi: 10.1038/s41467-020-14742-x
[19]	S. W. Koh, J. Hu, J. Hwang, P. Yu, Z. Sun, Q. Liu, W. Hong, J. Ge, J. Fei, and B. Han, Mater. Chem. Front. 5, 4970 (2021). doi: 10.1039/D0QM01113D
[20]	J. S. Lopez, R. A. Dagle, V. L. Dagle, C. Smith, and K. O. Albrecht, Catal. Sci. Technol. 9, 1117 (2019). doi: 10.1039/C8CY02297F
[21]	X. Y. Guo, X. S. Guo, and Y. Suzuki, ChemistrySelect 5, 528 (2020). doi: 10.1002/slct.201903665
[22]	J. Y. Zhang, E. Yoo, B. H. Davison, D. Liu, J. A. Schaidle, L. Tao, and Z. L. Li, Green Chem. 23, 9534 (2021). doi: 10.1039/D1GC02854E
[23]	X. Y. Guo, L. S. Guo, Y. Zeng, R. Kosol, X. H. Gao, Y. Yoneyama, G. H. Yang, and N. Tsubaki, Catal. Today 368, 196 (2021). doi: 10.1016/j.cattod.2020.04.047
[24]	E. Aghaei and M. Haghighi, Microporous Mesoporous Mater. 270, 227 (2018). doi: 10.1016/j.micromeso.2018.05.011
[25]	Y. T. He, L. J. Zhu, Y. H. Luo, M. H. Fan, M. Y. Yang, Y. H. Zhang, and Q. X. Li, Fuel Process. Technol. 213, 106674 (2021). doi: 10.1016/j.fuproc.2020.106674
[26]	Y. T. He, Y. H. Luo, M. Y. Yang, Y. H. Zhang, L. J. Zhu, M. H. Fan, and Q. X. Li, Appl. Catal. A Gen. 630, 118440 (2022). doi: 10.1016/j.apcata.2021.118440
[27]	X. J. Niu, J. Gao, Q. Miao, M. Dong, G. F. Wang, W. B. Fan, Z. F. Qin, and J. G. Wang, Micropor. Mesopor. Mat. 197, 252 (2014). doi: 10.1016/j.micromeso.2014.06.027
[28]	L. J. Zhu, Y. H. Luo, Y. T. He, M. Y. Yang, Y. H. Zhang, M. H. Fan, and Q. X. Li, Mol. Catal. 517, 112063 (2022). doi: 10.1016/j.mcat.2021.112063
[29]	Y. H. Luo, L. J. Zhu, Y. T. He, M. Y. Yang, Y. H. Zhang, M. H. Fan, and Q. X. Li, Cellulose 29, 303 (2022). doi: 10.1007/s10570-021-04285-9
[30]	Y. H. Zhang, X. P. Wu, Y. T. He, Y. H. Luo, M. Y. Yang, M. H. Fan, and Q. X. Li, J. Chem. Technol. Biotechnol. 97, 2068 (2022). doi: 10.1002/jctb.7077
[31]	M. Y. Yang, X. P. Wu, Y. T. He, Y. H. Luo, Y. H. Zhang, M. H. Fan, and Q. X. Li, Cellulose 29, 5557 (2022). doi: 10.1007/s10570-022-04625-3
[32]	Y. T. He, Y. H. Luo, M. Y. Yang, Y. H. Zhang, M. H. Fan, and Q. X. Li, Catal. Sci. Technol. 12, 4524 (2022). doi: 10.1039/D2CY00382A
[33]	C. P. Nash, A. Ramanathan, D. A. Ruddy, M. Behl, E. Gjersing, M. Griffin, H. D. Zhu, B. Subramaniam, J. A. Schaidle, and J. E. Hensley, Appl. Catal. A Gen. 510, 110 (2016). doi: 10.1016/j.apcata.2015.11.019
[34]	A. Martinez, M. A. Arribas, P. Concepcion, and S. Moussa, Appl. Catal. A Gen. 467, 509 (2013). doi: 10.1016/j.apcata.2013.08.021
[35]	S. X. Tian, S. F. Ji, D. D. Lu, B. Y. Bai, and Q. Sun, J. Energy Chem. 22, 605 (2013). doi: 10.1016/S2095-4956(13)60079-0
[36]	E. Aghaei and M Haghighi, Microporous Mesoporous Mater. 270, 227 (2018). doi: 10.1016/j.micromeso.2018.05.011
[37]	D. Z. Zhang, Y. X. Wei, L. Xu, F. X. Chang, Z. Y. Liu, S. H. Meng, B. L. Su, and Z. M. Liu, Microporous Mesoporous Mater. 116, 684 (2008). doi: 10.1016/j.micromeso.2008.06.001
[38]	A. G. Popov, V. S. Pavlov, and I. I. Ivanova, J. Catal. 335, 155 (2016). doi: 10.1016/j.jcat.2015.12.008
[39]	H. Konno, T. Tago, Y. Nakasaka, G. Watanabe, and T. Masuda, Appl. Catal. A Gen. 475, 127 (2014). doi: 10.1016/j.apcata.2014.01.031
[40]	T. Tago, H. Konno, M. Sakamoto, Y. Nakasaka, and T. Masuda, Appl. Catal. A Gen. 403, 183 (2011). doi: 10.1016/j.apcata.2011.06.029