An Apparatus for Investigating the Kinetics of Plasmonic Catalysis<sup>†</sup>

Wen Zhang; Yong Zhou; Wei Chen; Tianjun Wang; Zhaoxian Qin; Gao Li; Zefeng Ren; Xueming Yang; Chuanyao Zhou

doi:10.1063/1674-0068/cjcp2211160

Article Contents

Article Navigation > Chinese Journal of Chemical Physics > 2022 > Online First

Wen Zhang, Yong Zhou, Wei Chen, Tianjun Wang, Zhaoxian Qin, Gao Li, Zefeng Ren, Xueming Yang, Chuanyao Zhou. An Apparatus for Investigating the Kinetics of Plasmonic Catalysis†[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2211160

Citation:

Wen Zhang, Yong Zhou, Wei Chen, Tianjun Wang, Zhaoxian Qin, Gao Li, Zefeng Ren, Xueming Yang, Chuanyao Zhou. An Apparatus for Investigating the Kinetics of Plasmonic Catalysis^†[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2211160

Citation:

PDF( 174 KB)

An Apparatus for Investigating the Kinetics of Plasmonic Catalysis^†

doi: 10.1063/1674-0068/cjcp2211160

Wen Zhang^{1, 2},
Yong Zhou^{1
,
,},
Wei Chen^{2, 3},
Tianjun Wang²,
Zhaoxian Qin²,
Gao Li²,
Zefeng Ren²,
Xueming Yang²,
Chuanyao Zhou^{2, 3
,
,}

1.
Anhui Key Laboratory of Optoelectric Materials Science and Technology, Department of Physics, Anhui Normal University, Wuhu 241000, China
2.
State Key Laboratory of Molecular Reaction Dynamics, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

More Information

Corresponding author: E-mail: yong.zhou@mail.ahnu.edu.cn; chuanyaozhou@dicp.ac.cn
Received Date: 2022-11-02
Accepted Date: 2022-12-09

Available Online: 2022-12-13

Abstract

Abstract

Plasmonic catalysis, which is driven by the localized surface plasmon resonance of metal nanoparticles, has become an emerging field in heterogeneous catalysis. The microscopic mechanism of this kind of reaction, however, remains controversial partly because of the inaccuracy of temperature measurement and the ambiguity of reagent adsorption state. In order to investigate the kinetics of plasmonic catalysis, an online mass spectrometer-based apparatus has been built in our laboratory, with emphases on dealing with temperature measurement and adsorption state identification issues. Given the temperature inhomogeneity in the catalyst bed, three thermocouples are installed compared with the conventional design with only one. Such a multiple-point temperature measuring technique enables the quantitative calculation of equivalent temperature and thermal reaction contribution of the catalysts. Temperature-programmed desorption is incorporated into the apparatus, which helps to identify the adsorption state of reagents. The capabilities of the improved apparatus have been demonstrated by studying the kinetics of a model plasmon-induced catalytic reaction, i.e., H₂+D₂→HD over Au/TiO₂. Dissociative adsorption of molecular hydrogen at Au/TiO₂ interface and non-thermal contribution to HD production have been confirmed.
- Plasmonic catalysis,
- Reaction apparatus,
- Reaction mechanism,
- Driving force,
- Multiple-point temperature measureing,
- Adsorption state identification

Part of the special issue of ``the Chinese Chemical Society's 17th National Chemical Dynamics Symposium"

FullText(HTML)

References(37)

References

[1]	S. Galvagno and G. Parravano, J. Catal. 55, 178 (1978). doi: 10.1016/0021-9517(78)90204-X
[2]	M. Haruta, N. Yamada, T. Kobayashi, and S. Iijima, J. Catal. 115, 301 (1989). doi: 10.1016/0021-9517(89)90034-1
[3]	M. Haruta, Catal. Today 36, 153 (1997). doi: 10.1016/S0920-5861(96)00208-8
[4]	C. Ratnasamy and J. P. Wagner, Catal. Rev. 51, 325 (2009). doi: 10.1080/01614940903048661
[5]	W. J. Stark, P. R. Stoessel, W. Wohlleben, and A. Hafner, Chem. Soc. Rev. 44, 5793 (2015). doi: 10.1039/C4CS00362D
[6]	U. Aslam, V. G. Rao, S. Chavez, and S. Linic, Nat. Catal. 1, 656 (2018). doi: 10.1038/s41929-018-0138-x
[7]	P. Christopher, H. Xin, and S. Linic, Nat. Chem. 3, 467 (2011). doi: 10.1038/nchem.1032
[8]	M. C. Daniel and D. Astruc, Catal. Rev. 104, 293 (2004). doi: 10.1021/cr030698+
[9]	G. V. Hartland, Catal. Rev. 111, 3858 (2011). doi: 10.1021/cr1002547
[10]	S. Linic, U. Aslam, C. Boerigter, and M. Morabito, Nat. Mater. 14, 567 (2015). doi: 10.1038/nmat4281
[11]	C. Boerigter, R. Campana, M. Morabito, and S. Linic, Nat. Commun. 7, 1 (2016). doi: 10.1038/ncomms10545
[12]	P. Christopher, H. Xin, A. Marimuthu, and S. Linic, Nat. Mater. 11, 1044 (2012). doi: 10.1038/nmat3454
[13]	S. Mukherjee, F. Libisch, N. Large, O. Neumann, L. V. Brown, J. Cheng, J. B. Lassiter, E. A. Carter, P. Nordlander, and N. J. Halas, Nano Lett. 13, 240 (2013). doi: 10.1021/nl303940z
[14]	L. Zhou, D. F. Swearer, C. Zhang, H. Robatjazi, H. Zhao, L. Henderson, L. Dong, P. Christopher, E. A. Carter, P. Nordlander, and N. J. Halas, Science 362, 69 (2018). doi: 10.1126/science.aat6967
[15]	L. Zhou, C. Zhang, M. J. McClain, A. Manjavacas, C. M. Krauter, S. Tian, F. Berg, H. O. Everitt, E. A. Carter, P. Nordlander, and N. J. Halas, Nano Lett. 16, 1478 (2016). doi: 10.1021/acs.nanolett.5b05149
[16]	Y. Sivan, J. Baraban, I. W. Un, and Y. Dubi, Science 364, 9367 (2019). doi: 10.1126/science.aaw9367
[17]	Y. Sivan, J. H. Baraban, and Y. Dubi, OSA Continuum 3, 483 (2020). doi: 10.1364/OSAC.376809
[18]	Y. Dubi, I. W. Un, and Y. Sivan, Chem. Sci. 11, 5017 (2020). doi: 10.1039/C9SC06480J
[19]	X. Zhang, X. L. Li, M. E. Reish, D. Zhang, N. Q. Su, Y. Gutierrez Vela, F. Moreno, W. Yang, H. O. Everitt, and J. Liu, Nano Lett. 18, 1714 (2018). doi: 10.1021/acs.nanolett.7b04776
[20]	X. Li, X. Zhang, H. O. Everitt, and J. Liu, Nano Lett. 19, 1706 (2019). doi: 10.1021/acs.nanolett.8b04706
[21]	R. Cortright and J. Dumesic, Adv. Catal. 46, 161 (2001). doi: 10.1002/chin.200150264
[22]	S. Mukherjee, L. Zhou, A. M. Goodman, N. Large, C. Ayala-Orozco, Y. Zhang, P. Nordlander, and N. J. Halas, J. Am. Chem. Soc. 136, 64 (2014). doi: 10.1021/ja411017b
[23]	L. Zhou, C. Zhang, M. J. McClain, A. Manjavacas, C. M. Krauter, S. Tian, F. Berg, H. O. Everitt, E. A. Carter, P. Nordlander, and N. J. Halas, Nano Lett. 16, 1478 (2016). doi: 10.1021/acs.nanolett.5b05149
[24]	J. L. Falconer and J. A. Schwarz, Catal. Rev. Sci. Eng. 25, 141 (1983). doi: 10.1080/01614948308079666
[25]	J. Gong and C. B. Mullins, Acc. Chem. Res. 42, 1063 (2009). doi: 10.1021/ar8002706
[26]	A. V. Luikov, Analytical Heat Diffusion Theory, 1st Edn., New York: Elsevier-Science Direct, 1 (1968)
[27]	X. Du, Y. Huang, X. Pan, B. Han, Y. Su, Q. Jiang, M. Li, H. Tang, G. Li, and B. Qiao, Nat. Commun. 11, 1 (2020). doi: 10.1038/s41467-019-13993-7
[28]	S. K. Ghosh and T. Pal, Chem. Rev. 107, 4797 (2007). doi: 10.1021/cr0680282
[29]	M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M. J. Genet, and B. Delmon, J. Catal. 144, 175 (1993). doi: 10.1006/jcat.1993.1322
[30]	M. A. Henderson, W. S. Epling, C. H. Peden, and C. L. Perkins, J. Phys. Chem. B 107, 534 (2003). doi: 10.1021/jp0262113
[31]	X. Mao, X. Lang, Z. Wang, Q. Hao, B. Wen, Z. Ren, D. Dai, C. Zhou, L. M. Liu, and X. Yang, J. Phys. Chem. Lett. 4, 3839 (2013). doi: 10.1021/jz402053p
[32]	R. A. Ojifinni, N. S. Froemming, J. Gong, M. Pan, T. S. Kim, J. White, G. Henkelman, and C. B. Mullins, J. Am. Chem. Soc. 130, 6801 (2008). doi: 10.1021/ja800351j
[33]	T. Whittaker, K. S. Kumar, C. Peterson, M. N. Pollock, L. C. Grabow, and B. D. Chandler, J. Am. Chem. Soc. 140, 16469 (2018). doi: 10.1021/jacs.8b04991
[34]	C. Xu, W. Yang, Q. Guo, D. Dai, M. Chen, and X. Yang, J. Am. Chem. Soc. 135, 10206 (2013). doi: 10.1021/ja4030963
[35]	F. Li, X. Chen, Q. Guo, and X. Yang, J. Phys. Chem. C 124, 26965 (2020). doi: 10.1021/acs.jpcc.0c09520
[36]	A. G. Sault, R. J. Madix, and C. T. Campbell, Surf. Sci. 169, 347 (1986). doi: 10.1016/0039-6028(86)90616-3
[37]	K. B. Sravan Kumar, T. N. Whittaker, C. Peterson, L. C. Grabow, and B. D. Chandler, J. Am. Chem. Soc. 142, 5760 (2020). doi: 10.1021/jacs.9b13729