Improved Surface Acidity of Niobium Doped Tungstated-Zirconia Solid Acid Catalyst over Production of  5-Hydroxymethylfurfural

Xiaojun Wang; Ni Lu; Yuanyi Fu; Chang Lu; Meili Guan; Kunhua Wang; Hao Yu

doi:10.1063/1674-0068/cjcp2205093

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Xiaojun Wang, Ni Lu, Yuanyi Fu, Chang Lu, Meili Guan, Kunhua Wang, Hao Yu. Improved Surface Acidity of Niobium Doped Tungstated-Zirconia Solid Acid Catalyst over Production of 5-Hydroxymethylfurfural[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2205093

Citation:

Xiaojun Wang, Ni Lu, Yuanyi Fu, Chang Lu, Meili Guan, Kunhua Wang, Hao Yu. Improved Surface Acidity of Niobium Doped Tungstated-Zirconia Solid Acid Catalyst over Production of 5-Hydroxymethylfurfural[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2205093

Citation:

Xiaojun Wang, Ni Lu, Yuanyi Fu, Chang Lu, Meili Guan, Kunhua Wang, Hao Yu. Improved Surface Acidity of Niobium Doped Tungstated-Zirconia Solid Acid Catalyst over Production of 5-Hydroxymethylfurfural[J]. Chinese Journal of Chemical Physics . doi: 10.1063/1674-0068/cjcp2205093

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Improved Surface Acidity of Niobium Doped Tungstated-Zirconia Solid Acid Catalyst over Production of 5-Hydroxymethylfurfural

doi: 10.1063/1674-0068/cjcp2205093

Xiaojun Wang^{1, 2},
Ni Lu²,
Yuanyi Fu²,
Chang Lu²,
Meili Guan²,
Kunhua Wang^{1, 2
,
,},
Hao Yu^{1, 2
,
,}

1.
College of Energy Storage Technology, Shandong University of Science and Technology, Qingdao 266590, China
2.
College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China

More Information

Corresponding author: E-mail: wangkhua@mail.ustc.edu.cn; haoyu@sdust.edu.cn
Received Date: 2022-05-23
Accepted Date: 2022-09-15

Available Online: 2022-09-20

Abstract

Abstract

The 5-hydroxymethylfurfural (5-HMF) acts as an important chemical intermediate to bridge the biomass resources and industrial applications, which shows the potential for green development. However, the performance of biomass materials conversion to 5-HMF is still limited in the green solvent. Herein, an effective approach is reported to prepare the highly efficient solid acid catalysts, NbO_x /WO_y -ZrO₂, to improve fructose conversion. It is found that the introduction of Nb results in the generation of the niobium oxides, which improves acid sites and tunes the ratios of Brønsted acid and Lewis acid on the surface of the WO_y -ZrO₂ support. With the acidity improvement and increasing acid sites of the NbO_x /WO_y -ZrO₂, the highest fructose conversion is 99% in water. Meanwhile, the 5-HMF yield and the selectivity are also as high as 50.1% and 50.7% under the reaction temperature of 180 °C for a short reaction time of 30 min. The proposed NbO_x /WO_y -ZrO₂ catalyst strategy will not only open a new way for designing the solid acid catalysts to achieve high performance of the 5-HMF in the water, but also promote the green production of biomass and sustainable development in the future.
- Niobium oxide,
- Tungsten zirconia solid acid,
- Fructose,
- 5-Hydroxymethylfurfural,
- Acid site

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References(56)

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