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Volume 29 Issue 5
Oct.  2016
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Cheng-yun Gong, Zhi-gang Geng, An-le Dong, Xin-xin Ye, Guo-zhong Wang, Yun-xia Zhang. Highly Efficient and Selective Removal of Pb(II) ions by Sulfur-Containing Calcium Phosphate Nanoparticles[J]. Chinese Journal of Chemical Physics , 2016, 29(5): 607-616. DOI: 10.1063/1674-0068/29/cjcp1603045
Citation: Cheng-yun Gong, Zhi-gang Geng, An-le Dong, Xin-xin Ye, Guo-zhong Wang, Yun-xia Zhang. Highly Efficient and Selective Removal of Pb(II) ions by Sulfur-Containing Calcium Phosphate Nanoparticles[J]. Chinese Journal of Chemical Physics , 2016, 29(5): 607-616. DOI: 10.1063/1674-0068/29/cjcp1603045
shu

Highly Efficient and Selective Removal of Pb(II) ions by Sulfur-Containing Calcium Phosphate Nanoparticles

  • 1.

    Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China

  • 2.

    Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China

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  • Received Date: March 10, 2016
  • Revised Date: April 21, 2016
    Graphical Abstract
    • Abstract
  • A facile one-step co-precipitation method was demonstrated to fabricate amorphous sulfurcontaining calcium phosphate (SCP) nanoparticles, in which the sulfur group was in-situ introduced into calcium phosphate. The resulting SCP exhibited a noticeable enhanced performance for Pb(II) removal in comparison with hydroxyapatite (HAP), being capable of easily reducing 20 ppm of Pb(II) to below the acceptable standard for drinking water within less than 10 min. Remarkably, the saturated removal capacities of Pb(II) on SCP were as high as 1720.57 mg/g calculated by the Langmuir isotherm model, exceeding largely that of the previously reported absorbents. Significantly, SCP displayed highly selective removal ability toward Pb(II) ions in the presence of the competing metal ions (Ni(II), Co(II), Zn(II), and Cd(II)). Further investigations indicated that such ultra-high removal efficiency and preferable affinity of Pb(II) ions on SCP may be reasonably ascribed to the formation of rodlike hydroxypyromorphite crystals on the surface of SCP via dissolution-precipitation and ion exchange reactions, accompanied by the presence of lead sulfide precipitates. High removal efficiency, fast removal kinetics and excellent selectivity toward Pb(II) made the obtained SCP material an ideal candidate for Pb(II) ions decontamination in practical application.
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