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Volume 29 Issue 4
Aug.  2016
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Xiao-hu Wu, Hua Xie, Zhi-ling Liu, Hai-feng Su, Shui-chao Lin, Zi-chao Tang. A Reflectron Time-of-Flight Mass Spectrometer with a Nano-Electrospray Ionization Source for Study of Metal Cluster Compounds[J]. Chinese Journal of Chemical Physics , 2016, 29(4): 401-406. DOI: 10.1063/1674-0068/29/cjcp1601019
Citation: Xiao-hu Wu, Hua Xie, Zhi-ling Liu, Hai-feng Su, Shui-chao Lin, Zi-chao Tang. A Reflectron Time-of-Flight Mass Spectrometer with a Nano-Electrospray Ionization Source for Study of Metal Cluster Compounds[J]. Chinese Journal of Chemical Physics , 2016, 29(4): 401-406. DOI: 10.1063/1674-0068/29/cjcp1601019
shu

A Reflectron Time-of-Flight Mass Spectrometer with a Nano-Electrospray Ionization Source for Study of Metal Cluster Compounds

  • 1.

    State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

  • 2.

    School of Chemistry & Material Science, Shanxi Normal University, Linfen 041004, China

  • 3.

    State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

  • 4.

    State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

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  • Received Date: January 25, 2016
  • Revised Date: February 29, 2016
    Graphical Abstract
    • Abstract
  • An experiment facility has been set up for the study of metal cluster compounds in our laboratory, which consists of a nano-electrospray ionization source, an ion transmission and focus system, and a reflectron time-of-flight mass spectrometer. Taking advantage of the nano-electrospray ionization source, polyvalent ions are usually produced in the “ionization” process and the obtained mass resolution of the equipment is over 8000. The molecular ion peaks of metal cluster compounds [Au20(PPhpy2)10Cl2](SbF6)4, where PPhpy2=bis(2-pyridyl)phenylphosphine, and [Au6Ag2(C)L6](BF4)4, where L=2-(diphenylphosphino)-5-methylpyridine, are distinguished in the respective mass spectrum, accompanied by some fragment ion peaks. In addition, the mass-to-charge ratios of the parent ions are determi-nated. Preliminary results suggest that the device is a powerful tool for the study of metal cluster compounds. It turns out that the information obtained by the instrumentation serves as an essential supplement to single crystal X-ray diffraction for structure characterization of metal cluster compounds.
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    • References (28)
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