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    Chun-yan Li, Ting-ting Wang, Jun-feng Zhen, Yang Chen, Zhi-wei He. Line-profile Analysis of Excitation Spectroscopy in Even 5p5(2P1/2)nl' [K']J (l'=1, 3) Autoionizing Resonances of Xe[J]. Chinese Journal of Chemical Physics , 2013, 26(4): 374-380. DOI: 10.1063/1674-0068/26/04/374-380
    Citation: Chun-yan Li, Ting-ting Wang, Jun-feng Zhen, Yang Chen, Zhi-wei He. Line-profile Analysis of Excitation Spectroscopy in Even 5p5(2P1/2)nl' [K']J (l'=1, 3) Autoionizing Resonances of Xe[J]. Chinese Journal of Chemical Physics , 2013, 26(4): 374-380. DOI: 10.1063/1674-0068/26/04/374-380

    Line-profile Analysis of Excitation Spectroscopy in Even 5p5(2P1/2)nl' K'J (l'=1, 3) Autoionizing Resonances of Xe

    • The even-parity autoionizing resonance series 5p5np'3/21, 1/21, and 5p5nf'5/23 of xenon have been investigated, excited from the two metastable states 5p56s3/22 and 5p56s'1/20 in the photon energy range of 28000-42000 cm-1 with experimental bandwidth of ~0.1 cm-1. The excitation spectra of the even-parity autoionizing resonance series show typical asymmetric line shapes. New level energies, quantum defects, line profile indices and resonance widths, resonance lifetimes and reduced widths of the autoionizing resonances are derived by a Fano-type line-shape analysis. The line profile index and the resonance width are shown to be approximately proportional to the effective principal quantum number. The line separation of the 5p5np' autoionizing resonances is discussed.
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