Chinese Journal of Chemical Physics  2018, Vol. 31 Issue (1): 117-122

The article information

Ai-guo Mo, Yu-pu Wang, Yi-kun Liu, Wan-fu Zhou, Quan Zhou, Akram Yasin, Hai-yang Yang
莫爱国, 王玉普, 刘义坤, 周万富, 周泉, 艾克热木·牙生, 杨海洋
Enhanced Viscosity of Poly(acrylamide) Solution in the Presence of Chromium Citrate Triggered by Release of CO2
利用二氧化碳的缓慢释放控制聚丙烯酰胺在含柠檬酸铬水溶液中的粘度
Chinese Journal of Chemical Physics, 2018, 31(1): 117-122
化学物理学报, 2018, 31(1): 117-122
http://dx.doi.org/10.1063/1674-0068/31/cjcp1706128

Article history

Received on: June 28, 2017
Accepted on: August 1, 2017
Enhanced Viscosity of Poly(acrylamide) Solution in the Presence of Chromium Citrate Triggered by Release of CO2
Ai-guo Moa, Yu-pu Wanga, Yi-kun Liua, Wan-fu Zhoub, Quan Zhoub, Akram Yasinc, Hai-yang Yangc     
Dated: Received on June 28, 2017; Accepted on August 1, 2017
a. School of Petroleum Engineering, Northeast Petroleum University, Daqing 163453, China;
b. Oil Production Technology Institute, Daqing Oilfield Company. Ltd., Daqing 163453, China;
c. School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China
*Author to whom correspondence should be addressed. Hai-yang Yang, E-mail:yhy@ustc.edu.cn
Abstract: Partially hydrolyzed polyacrylamide (HPAM) has been widely used for water shut-off and profile control to enhance oil recovery. Herein, we reported a novel technique by which the crosslinking between HPAM and Cr3+ in aqueous solutions at 60 ℃ can be delayed effectively. Citric acid was selected as an organic complexing agent of Cr3+ so that the crosslinking between HPAM and Cr3+ can be prevented completely. Due to the decomposition of the bicarbonate (HCO3-) embedded in solution, CO2 released from solution and the pH value of solution increased gradually. The degree of ionization of HPAM and its ability to complex with Cr3+ increased accordingly. When the complexation of Cr3+ with HPAM is stronger than that with citric acid, the viscosity of the HPAM solution increased significantly. Under the closed condition, together with the existence of potassium dihydrogen phosphate (KH2PO4), the release of CO2 was very slow and the condition was highly controlled so that the ionization of HPAM was prevented initially. Furthermore, the hydrogen bonding interactions between HPAM and melamine embedded in solution previously also postponed the ionization of HPAM. As a result, the crosslinking between HPAM and Cr3+ can be delayed for almost one month, completely meeting the requirements for deep water shut-off and profile control to enhance oil recovery.
Key words: Polyacrylamide    Delayed cross-linking    pH responsibility    Complexation    
Ⅰ. INTRODUCTION

Intelligent fluids and their response to external stimuli have drawn significant attention in recent years. For the study of intelligent fluids, different kinds of adjustable stimuli are widely used, including: light [1-3], heat [4-6], pH [7-11], redox [12, 13], CO$_2$ [14-16], and so on. Compared to other stimulation methods, the regulation of pH is simple and more effective. For example, Feng et al. [7] prepared a ready-to-use intelligent fluid fabricated by a pH-switchable wormlike micelle system, of which the viscosity could be adjusted by tuning the pH through the addition of few acids or bases. Under acidic conditions, $N$-erucamidopropyl-$N$, $N$-dimethylamine (UC22AMPM) and maleic acid complexed with each other by electrostatic interaction to form worm-like micelles, as a result, the viscosity of the solution maintain a high level. When the pH exceeded 6.51, due to the deprotonation of UC22AMPM, worm-like micelles dissociated and the viscosity decreased rapidly. In addition, by combining the hydrophobic polyacrylamide with potassium oleate, and based on the assembly behavior of potassium oleate controlled by pH, Hao et al. [11] obtained an intelligent fluid that showed fascinating pH-responsive abilities. Furthermore, if the hydrophobic polyacrylamide was complexed with the cyclodextrin, an intelligent fluid [6] responsive to temperature can be obtained.

Zhang et al. [16] reported an intelligent fluid that can respond to CO$_2$, which was fabricated by mixing a tertiary amine-containing triblock polymer with nanoclay. In fact, this smart fluid, by its nature, showed pH responsive ability. Liu et al. [9] also reported a pH-responsive wormlike nanostructured fluid. However, the method to change the pH of the systems was confined due to the addition of acids or bases, which greatly limited their applications in a closed system such as in reservoir. Water shut-off and profile control is an important and effective method to enhance oil recovery. Due to its low-cost, water solubility, and excellent ability to crosslink with a variety of metal ions [17-22], partially hydrolyzed polyacrylamide (HPAM) has been widely used for water shut-off and profile control. To facilitate the injection and transportation of aqueous HPAM solution in the presence of metal ions, the crosslinking between HPAM and metal ions has to be delayed. The traditional technique is to add organic complexing agent such as lactic acid to trap the metal ions in advance to delay the release of the metal ions. For this purpose, the usual method is adding organic complexing agents such as lactic acid and citric acid to the system, through the introduction of the complexation of lactic acid or citric acid with metal ions, the time required to form crosslinking structure between polyacrylamide and metal ions can be prolonged and controlled [23-26]. Willhite et al. [23] embed Cr$^{3+}$ in the nanoparticles formed by self-assembly of polyethyleneimine and dextran sulfate, and the chromium efficiently sequestered in nanosuspensions could be slowly released to crosslink the HPAM based on the change of temperature, ionic strength and so on, resulting in a significant delay in crosslinking. So far, the time required to delay the crosslinking of polyacrylamide and metal ions is usually limited within one week. Moreover, with the increase of temperature, the shrinkage in the time of delaying crosslinking made it more difficult to meet the technical requirements for enhanced oil recovery.

Herein, we reported a novel technique by which the crosslinking between HPAM and Cr$^{3+}$ in aqueous solutions at 60 ℃ can be delayed for almost one month. In our experiments, citric acid was selected as an organic complexing agent of Cr$^{3+}$ so that the crosslinking between HPAM and Cr$^{3+}$ can be prevented completely. Due to the decomposition of the bicarbonate (HCO$_3^{-}$) embedded deliberately in solution, CO$_2$ released from solution and the pH value of solution increased gradually. The degree of ionization of HPAM and its ability to complex with Cr$^{3+}$, therefore, increased accordingly. When the complexation of Cr$^{3+}$ with HPAM is stronger than that with citric acid, the viscosity of the HPAM solution increased significantly. However, under the closed condition, together with the existence of potassium dihydrogen phosphate (KH$_2$PO$_4$), the release of CO$_2$ was very slow so that the ionization of HPAM was prevented effectively. Furthermore, the hydrogen bonding interactions between HPAM and melamine embedded in solution also postponed the ionization of HPAM. As a result, the crosslinking between HPAM and Cr$^{3+}$ can be delayed for almost one month. The similar results have never been reported previously.

Ⅱ. EXPERIMENTS A. Materials

Partially hydrolyzed polyacrylamide (the degree of hydrolysis 21 mol%), citric acid chromium, potassium dihydrogen phosphate, sodium bicarbonate and melamine were purchased from Sinopharm Chemical Reagent Co. Ltd. All materials were analytical reagents and used as received.

B. Preparation of HPAM solutions

NaCl (0.5 g) was dissolved in 100 mL deionized water, followed by addition of HPAM (0.05 g) slowly. After stirring 2 h, a transparent and uniform solution was obtained. Then, thiourea (0.05 g), chromium citrated (0.2 g), melamine (0.05 g), sodium bicarbonate (0.3 g), and potassium dihydrogen phosphate (0.2 g) were added to the above solution. After stirring for 30 min, the solution was transferred into the glass bottle, and finally the bottle was sealed.

C. Rheological measurements

Rheological measurements were conducted on a TA AR-G2 rheometer using a cone-plate of 40 mm diameter with a cone angle of 1$^\circ$. The shear rate was set to be 0.451 s$^{-1}$, 6 data points per minute, 5 min in total, and was taken the average.

D. pH variation measurements

A mixed solution of 0.3 wt% sodium bicarbonate and 0.2 wt% potassium dihydrogen phosphate was prepared. The pH was measured every one hour with an electronic pH tester at different temperatures.

Ⅲ. RESULTS AND DISCUSSION A. Effects of lactic acid and citric acid on the gelation properties of HPAM-Cr(Ⅲ) system

As a common thickener, HPAM-Cr(Ⅲ) crosslinking system has been widely used in oil extraction engineering. When Cr$^{3+}$ dissolved in water, Cr$^{3+}$ will go through hydration, hydrolysis, hydroxylation, further hydrolysis and further hydroxylation process, finally form multi-core hydroxyl bridge chromium ions, as shown in FIG. 1(a). If HPAM exists, the chromium-containing ligand will complex with the carboxyl group in HPAM as shown in FIG. 1(b), then different polyacrylamide molecules will be crosslinked to achieve the purpose of thickening [18, 27, 28]. In the process of water shutoff and profile control, in order to inject the crosslinked HPAM into the target layer, it is necessary to control the crosslinking degree between HPAM and Cr$^{3+}$ to reduce the initial viscosity, after it is injected into the target layer, the crosslinking between HPAM and Cr$^{3+}$ will come about and increase gradually to raise the final viscosity, for this purpose, the most common practice is to add lactic acid or citric acid into the solution, then the Cr$^{3+}$ acting as a cross linker will complex with citric acid or lactic acid at first, as an alternative method, lactic acid chromium or lemon chromium can be prepared as a crosslinking agent from the start.

FIG. 1 (a) The formation process of multi-core hydroxyl bridge chromium ions. (b) The gelling mechanism of HPAM and multi-core hydroxyl bridge chromium ions.

In the water, lactic acid chromium or lemon chromium will gradually ionize to produce trivalent chromium ions, as follows:

$ \begin{eqnarray} &&\rm{Cr}(\rm{C}_3\rm{H}_5\rm{O}_3)_3\rightleftharpoons \rm{Cr}^{3+}+{3\rm{C}_3\rm{H}_5\rm{O}_3}^-\nonumber\\ &&\rm{CrC}_6\rm{H}_5\rm{O}_7\rightleftharpoons \rm{Cr}^{3+}+{\rm{C}_6\rm{H}_5\rm{O}_7}^{3-}\nonumber \end{eqnarray} $

The Cr$^{3+}$ then hydrolyzes stepwise as shown in FIG. 1 and crosslinks with the carboxyl groups in the HPAM. The ionization process of lactic acid chromium or lemon chromium is slow, as a result, adding lactic acid or citric acid can effectively delay the gelation time of Cr$^{3+}$ and HPAM. Adding organic complexes can delay the cross-linking of HPAM and Cr$^{3+}$, and the ability to delay the cross-linking depends on their complexation constant and temperature. The complexation constants are 1.2, 3.3, 3.7, 4.7, 5.4, and 7.69 for salicylic acid, lactic acid, acetic acid, propionic acid, malic acid, and citric acid, respectively. We can see that the complexation constant of lactic acid is relatively small and the complexation constant of citric acid is the largest. The stronger complexation between organic complexes and Cr$^{3+}$, the longer the time required to delay the crosslinking of HPAM and Cr$^{3+}$. On the other hand, the higher environment temperature is, the shorter delay time will be realized. According to the current literatures [23, 26], the addition of citric acid can prolong the crosslinking time of HPAM-Cr$^{3+}$ system to 1$-$2 days at 90 ℃. Considering the situation in Daqing Oilfield, the temperature of most reservoirs is about 60 ℃. According to the actual engineering requirements, the time needed to crosslink HPAM and Cr$^{3+}$ should be prolonged to over one month. To solve this problem, we here used lactic acid and citric acid to control the cross-linking time of HPAM-Cr$^{3+}$ system. It was demonstrated that the system would be cross-linked rapidly by using lactic acid as organic complex in the oven at 60 ℃, while the system did not produce cross-linking for one month by using citric acid. And there would not be any cross-linking with the further prolongation of time (FIG. 2), by adding both lactic acid and citric acid into the system and further adjusting their ratios, it showed that there existed neither immediate cross-linking, nor delaying cross-linking indicating that no matter what ligand was selected, the time needed for the cross-linking of HPAM and Cr$^{3+}$ could not be prolonged to over one month at 60 ℃ in the closed conditions. In order to solve this technical problem, we should find another method.

FIG. 2 The comparison pictures of HPAM-Cr$^{3+}$ system (a) without citric acid and (b) with citric acid.
B. Effects of pH on gelation properties of HPAM/lactic acid chromium system

It can be seen from FIG. 1(b) that the complexation between HPAM and Cr$^{3+}$ is essentially a coordination cross-link of carboxylate ions rather than carboxylic acid with Cr$^{3+}$, similarly, the complexation between lactic acid or citric acid and Cr$^{3+}$ is also a coordination cross-link of carboxylate ions with Cr$^{3+}$. Therefore these interactions coexsit and compete with each other in the aqueous phase. Because the charge repulsion between carboxylate ions in HPAM's polymer chains is evidently larger than that of small molecules, it is difficult for carboxylic acid's ionization degree of HPAM to match that of small molecules, which limits the complexation of HPAM and Cr$^{3+}$. Then the added orgnic complexes such as citric acid can complex with chromium ions strongly, resulting in limited ionized chromium ions, so that the HPAM-Cr$^{3+}$ system does not produce any cross-linking at 60 ℃ in the presence of citric acid and the crosslinking time can be controlled for more than one month. By raising the pH of the system, the carboxyl groups in HPAM will be increasingly ionized to form carboxylate ions, and the complexation between the polyacrylamide and chromium ions will be significantly enhanced, and the resulting complexes tend to be more competitive. Therefore, HPAM-Cr$^{3+}$ system has pH responsive ability. In order to verify our judgment, we determined the change of the viscosity of HPAM-Cr$^{3+}$ system with pH after 24 h in an enclosed enviroment at 60 ℃. The results are shown in FIG. 3, it can be seen from the figure that when the pH was low (pH=5 or 6), the viscosity of the system was almost the same as that of water, indicating that the cross-linking reaction didn't happen in the system. When the pH was increased to 7, the viscosity of the system rose slightly to about 50 mPa$\cdot$s, indicating that only a slight cross-linking reaction occured at this time. Further increasing the pH of the system to 8, the viscosity of the system increased significantly after 24 h, reaching about 2700 mPa$\cdot$s. With the further increase of pH, the viscosity of the system decreased from 2200 mPa$\cdot$s at pH=9 to about 20 mPa$\cdot$s at pH=10. The above results showed that pH had a significant effect on the gelation properties of HPAM/lactic acid chromium system.

FIG. 3 The changes of the viscosity of HPAM-Cr$^{3+}$ system with the pH.

Due to the much stronger complexation interaction between citric acid and Cr$^{3+}$ than that between HPAM and Cr$^{3+}$, a higher pH condition should be achieved which was in favor of the crosslinking between HPAM and Cr$^{3+}$. The experimental results of FIG. 3 have shown that the HPAM-Cr$^{3+}$ system did not produce any cross-links at 60 ℃ in the presence of citric acid, even if the time prolonged to over one month. If bicarbonate ions were engaged in the HPAM-Cr$^{3+}$ system, the pH of the system could be changed resulting from the gradually released CO$_2$ by bicarbonate ions under heating conditions, which possibly triggered the cross-linking of HPAM with Cr$^{3+}$. If pH buffer such as potassium dihydrogen phosphate was added into the system, and in a completely closed system, the time required to delay the crosslinking of HPAM-Cr$^{3+}$ system in the presence of citric acid could possibly be prolonged to over one month.

C. Effects of release of CO$_{2}$ on the pH

In order to use the release of CO$_2$ to change the pH, we dissolved sodium bicarbonate (NaHCO$_3$) in the HPAM/citric acid chromium system. To better control the change rate of the pH, we added potassium dihydrogen phosphate (KH$_2$PO$_4$)/sodium bicarbonate (NaHCO$_3$) as a pH buffer into this system. This pH buffer could not only maintain the system at a low pH for a long time, but also produce CO$_2$ through the reaction of KH$_2$PO$_4$ with NaHCO$_3$, after CO$_2$ escaped from the solution, the pH of the system increased gradually.

To verify the assumptions mentioned above, the changes of the pH with time for the mixed solution of KH$_2$PO$_4$ and NaHCO$_3$ at different temperature were measured, of which the concentrations of KH$_2$PO$_4$ and NaHCO$_3$ were 0.1% and 0.3%, respectively. For the mixed solution at 45 and 70 ℃, respectively, the initial pH was about 6.8, which was comparable to the pH of the solution prepared in situ, and the results are shown in FIG. 4. It can be seen from the figure that the pH of the mixed solution gradually increased to 7.5 at 45 ℃ and 7.9 at 70 ℃ in 7 h, respectively. These results verified the correctness of our idea that the pH buffer solution consisting of KH$_2$PO$_4$ and NaHCO$_3$ could initially maintain the system at a low pH, as time went by, the CO$_2$ generated by the reaction of KH$_2$PO$_4$ and NaHCO$_3$ escaped from the solution, then the pH of the system increased gradually. As the temperature was further increased to 90 ℃, the pH of the system changed faster.

FIG. 4 The changes of the pH with time for the solution consisting of 0.1% sodium dihydrogen phosphate and 0.3% sodium bicarbonate at different temperatures.

It is important to note that in order to facilitate the measurement in the above-mentioned verification test, the airtightness of the system was not good, and this factor accelerated the escape speed of the generated CO$_2$, as a result, the pH of the mixed solution of KH$_2$PO$_4$ and NaHCO$_3$ increased fast. While the system was airtight, due to the slow escape speed of CO$_2$, the pH buffer consisting of KH$_2$PO$_4$ and NaHCO$_3$ maintained the system at a low pH for a longer time, and thus the gelling process of HPAM-Cr$^{3+}$ could be delayed and controlled effectively. FIG. 5 shows the change of viscosity with time for the HPAM / citric acid chromium system with 0.1% KH$_2$PO$_4$/0.3% NaHCO$_3$ at 60 ℃. It can be seen from the results that the viscosity of the system at the initial state was less than 40 mPa$\cdot$s, and it remained almost constant or increased only a little over time. However, when the time was prolonged to 30 days, the viscosity of the system was obviously larger than that at the beginning, and the viscosity reached a maximum of 2299 mPa$\cdot$s after 40 days. With the further prolongation of time, although the viscosity of the system decreased slightly, it was still above 2000 mPa$\cdot$s. Along with the measurements of the viscosity, we also measured the pH of the sealed sample, the results indicated that the pH of the sample maintained at 7 to 8 for the first 20 days while it increased to 8 to 9 after 1 month, which was consistent with our expectation. It can be seen that there still exited small amount of CO$_2$ escaping from the solution to the cavity of the tube. As a consequence, the pH of the solution increased slowly, and the complexation between HPAM and Cr$^{3+}$ was gradually activated, then the viscosity of the system accordingly increased. The escape rate of CO$_2$ could be decelerated in the presence of KH$_2$PO$_4$ in a closed system at 60 ℃. In turn, the complexation between HPAM and Cr$^{3+}$ was delayed effectively. This novel method we report here can prolong the cross-linking time to over one month in a closed system at 60 ℃, and amazingly the final viscosity of the system can be maintained above 2000 mPa$\cdot$s, which was much more excellent than previously reported ones and, more importantly, meet the engineering requirements.

FIG. 5 The change of the viscosity of the HPAM/citric acid chromium system with time.
D. Control of melamine on the proton hydrogen of partially hydrolyzed polyacrylamide (HPAM)

Although the cross-linking time of HPAM/citric acid chromium system could be prolonged to more than one month after adding NaHCO$_3$ and KH$_2$PO$_4$ in a closed system at 60 ℃, the initial viscosity of the system was still relatively high, while the ideal water shutoff profile control agent should have both low initial viscosity and high final viscosity. For this purpose, a certain amount of melamine was added into the system. According to the literatures [29, 30], melamine can combine with the carboxyl groups in the polymer (-COOH) by hydrogen bonding interactions. If there was a certain amount of melamine in the system, the melamine will interact with HPAM through hydrogen bonds, as shown in FIG. 6, resulting in more curled polymer chains, and then the initial viscosity of the system will decrease. In addition, because the hydrogen proton in the polymer carboxyl group will be "confined" through the formation of hydrogen bond between melamine and polyacrylamide, it will be more difficult for the polyacrylamide to ionize. Therefore the complexation between polyacrylamide and chromium ions will be inhibited, and finally the cross-linking of the system can be delayed effectively.

FIG. 6 Photographs and schematic illustration of the carboxylic acid groups in HPAM "bonded" by melamine through hydrogen bonds.

In order to verify this idea, a certain amount of melamine was added to the HPAM/citric acid chromium system, which contained a pH buffer solution consisting of 0.1% KH$_2$PO$_4$ and 0.3% NaHCO$_3$, as shown in FIG. 7. The changes of the viscosity with time for the mixture with and without melamine in a closed system at 60 ℃ was measured. And it can be seen that after adding melamine, the initial viscosity of the system decreased to 10 mPa$\cdot$s, while the final viscosity remained almost the same, which can fully meet the requirements of engineering. Comparing the data points with and without melamine in FIG. 7, a significantly right shift can be observed after adding melamine, indicating that melamine could delay the complexation between polyacrylamide and chromium ions. Due to the positive correlation between the increase of the pH and the crosslinking of the carboxylate groups in the polymer chain with chromium ions, the carboxylic acid groups "bonded" by melamine through hydrogen bonds were gradually released and converted into carboxylate ions. And the final number of carboxylate ions that could participate in the cross-linking reaction, which was not affected by melamine. So the final gel strength of the system remained unchanged.

FIG. 7 The effects of the addition of melamine on the gelation properties of HPAM/citric acid chromium system.
Ⅳ. CONCLUSION

We have studied the viscosity of HPAM solution in the presence of Cr$^{3+}$ at 60 ℃. We found with astonishment that by dissolving citric acid into solution the crosslinking between polyacrylamide (PAM) and Cr$^{3+}$ could be prevented completely. Due to the decomposition of the bicarbonate (HCO$_3^{-}$) embedded deliberately in solution, CO$_2$ released from solution and the pH value of solution increased gradually. The degree of ionization of HPAM and its ability to complex with Cr$^{3+}$, therefore, increased accordingly. When the complexation of Cr$^{3+}$ with HPAM is stronger than that with citric acid, the viscosity of the HPAM solution increased significantly. Under the closed condition, together with the existence of potassium dihydrogen phosphate (KH$_2$PO$_4$), the release of CO$_2$ was very slow and the condition was highly controlled so that the ionization of HPAM was prevented initially. Furthermore, the hydrogen bonding interactions between HPAM and melamine embedded in solution previously also postponed the ionization of HPAM. As a result, the crosslinking between HPAM and Cr$^{3+}$ can be delayed for almost one month, completely meeting the requirements for deep water shut-off and profile control to enhance oil recovery.

Ⅴ. ACKNOWLEDGEMENTS

This work was supported by the National Natural Science Foundation of China (No.51273189), the National Science and Technology Major Project of the Ministry of Science and Technology of China (No.2016ZX05016), and the National Science and Technology Major Project of the Ministry of Science and Technology of China (No.2016ZX05046).

Reference
[1] H. Y. Lee, K. K. Diehn, K. S. Sun, T. H. Chen, and S. R. Raghavan, J. Am. Chem. Soc. 133 , 8461 (2011). DOI:10.1021/ja202412z
[2] T. S. Davies, A. M. Ketner, and S. R. Raghavan, J. Am. Chem. Soc. 128 , 6669 (2006). DOI:10.1021/ja060021e
[3] F. Peng, G. Z. Li, X. X. Liu, S. Z. Wu, and Z. Tong, J. Am. Chem. Soc. 130 , 16166 (2008). DOI:10.1021/ja807087z
[4] J. M. J. Paulusse, and R. P. Sijbesma, Angew. Chem. Int. Ed. 45 , 2334 (2006). DOI:10.1002/(ISSN)1521-3773
[5] C. Morita, Y. Imura, T. Ogawa, H. Kurata, and T. Kawai, Langmuir 29 , 5450 (2013). DOI:10.1021/la400604m
[6] X. Hao, W. F. Zhou, R. C. Yao, Y. J. Xie, S. U. Rehman, and H. Y. Yang, J. Mater. Chem. A 1 , 14612 (2013). DOI:10.1039/c3ta13250a
[7] Z. L. Chu, and Y. J. Feng, Chem. Commun. 46 , 9028 (2010). DOI:10.1039/c0cc02415e
[8] H. S. Lu, L. Wang, and Z. Y. Huang, RSC Adv. 4 , 51519 (2014). DOI:10.1039/C4RA08004A
[9] H. S. Lu, Q. P. Shi, and Z. Y. Huang, J. Phys. Chem. B 118 , 12511 (2014). DOI:10.1021/jp506809m
[10] W. L. Kang, P. X. Wang, H.M. Fan, H. B. Yang, C. L. Dai, X. Yin, Y. L. Zhao, and S. J. Guo, Soft Matter 13 , 1182 (2017). DOI:10.1039/C6SM02655A
[11] X. Hao, H. Liu, Z. Lu, Y. J. Xie, and H. Y. Yang, J. Mater. Chem. A 1 , 6920 (2013). DOI:10.1039/c3ta10285h
[12] X. Y. Chang, Z. K. Du, F. Y. Hu, Z. Y. Cheng, B. Y. Ren, S. Y. Fu, and Z. Tong, Langmuir 32 , 12137 (2016). DOI:10.1021/acs.langmuir.6b03508
[13] L. Z. Zhu, Y. G. Shangguan, Y. X. Sun, J. Ji, and Q. Zheng, Soft Matter 6 , 5541 (2010). DOI:10.1039/c0sm00246a
[14] Y. M. Zhang, Y. J. Feng, Y. J. Wang, and X. L. Li, Langmuir 29 , 4187 (2013). DOI:10.1021/la400051a
[15] J. Z. Jiang, G. Z. Wang, Y. X. Ma, Z. G. Cui, and B. P. Binks, Soft Matter 13 , 2727 (2017). DOI:10.1039/C7SM00185A
[16] L. Zhang, J. S. Qian, Y. J. Fan, W. Feng, Z. Tao, and H. Y. Yang, RSC Adv. 5 , 62229 (2015). DOI:10.1039/C5RA10597H
[17] C. Allain, and L. Salome, Macromolecules 23 , 981 (1990). DOI:10.1021/ma00206a015
[18] R. Jain, C. S. McCool, D. W. Green, G. P. Willhite, and M. J. Michnick, SPE J. 10 , 247 (2005). DOI:10.2118/89399-PA
[19] A. A. Al-Assi, G. P. Willhite, D. W. Green, and C. S. McCool, SPE J. 14 , 450 (2009). DOI:10.2118/100049-PA
[20] C. L. Dai, G. Zhao, Q. You, and M. W. Zhao, J. Appl. Polym. Sci. 131 , 631 (2013).
[21] W. S. Cai, and R. H. Huang, Eur. Polym. J. 37 , 1553 (2001). DOI:10.1016/S0014-3057(01)00041-6
[22] W. S. Cai, and R. H. Huang, Polym J. 33 , 330 (2001). DOI:10.1295/polymj.33.330
[23] M. Cordova, M. Cheng, J. Trejo, S. J. Johnson, G. P. Willhite, J. T. Liang, and C. Berkland, Macromolecules 41 , 4398 (2008). DOI:10.1021/ma800211d
[24] S. Jayakumar, and R. H. Lane, SPE J. (2113).
[25] P. Albonico, G. Burrafato, and T. P. Lockhart, J. Polym. Sci., Part A 30 , 1071 (1992). DOI:10.1002/pola.1992.080300612
[26] A. Moradi-Araghi, D. H. Beardmore, and G. A. Stahl, Water-Soluble Polymers for Petroleum Recovery. Boston, MA: Springer US , 299 (1988).
[27] L. Zhang, C. S. Pu, H. B. Sang, and Q. Zhao, Energy Fuels 29 , 4701 (2015). DOI:10.1021/acs.energyfuels.5b00149
[28] Y. Z. Hamada, N. Bayakly, A. Peipho, and B. Carlson, Synth. React. Inorg, Met. Org. Chem. 36 , 469 (2006). DOI:10.1080/15533170600777960
[29] P. A. Song, Z. G. Xu, and Q. P. Guo, ACS Macro Lett. 2 , 1100 (2013). DOI:10.1021/mz4005265
[30] G. Li, Q. Yan, H. S. Xia, and Y. Zhao, ACS Appl. Mater. Interfaces 7 , 12067 (2015). DOI:10.1021/acsami.5b02234
利用二氧化碳的缓慢释放控制聚丙烯酰胺在含柠檬酸铬水溶液中的粘度
莫爱国a, 王玉普a, 刘义坤a, 周万富b, 周泉b, 艾克热木·牙生c, 杨海洋c     
a. 东北石油大学石油工程学院, 大庆 163318;
b. 大庆油田有限责任公司采油工程研究院, 大庆 163453;
c. 中国科学技术大学化学与材料学院, 合肥 230026
摘要: 部分水解聚丙烯酰胺广泛用在堵水调剖以提高石油采收率等采油工程领域.本文报道了一种可以有效延缓部分水解聚丙烯酰胺在60℃水中与铬离子交联的新技术.首先利用柠檬酸和铬离子之间的络合来有效阻止部分水解聚丙烯酰胺与铬离子之间的交联作用,随着包埋在水溶液中碳酸氢根离子分解释放二氧化碳,溶液的pH值逐渐增加,导致部分水解聚丙烯酰胺电离度增加,因此与铬离子的交联作用也逐渐增强.当部分水解聚丙烯酰胺与铬离子的交联作用大于铬离子与柠檬酸之间络合作用时,溶液的黏度逐渐增加.在封闭条件下,以及由于磷酸二氢钾的缓冲作用,二氧化碳的释放是缓慢进行的,而三聚氰胺与部分水解聚丙烯酰胺氢键相互作用又进一步阻止了羧基的电离,因此部分水解聚丙烯酰胺与铬离子的交联作用可以被延缓到近一个月的时间,完全满足了利用深度堵水调剖方法提高石油采收率的工程技术要求.
关键词: 聚丙烯酰胺    延缓交联    pH值响应    络合作用